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Structure and Reactivity of a Stable Oxirane Derived from 2,2,6,6-Tetrachloro-3,3,5-Trimethylcyclohexanone and Methanolic Sodium Methoxide

✍ Scribed by Laurent De Buyck; Marc Dewaele; Norbert De Kimpe; Roland Verhé; Niceas Schamp

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
548 KB
Volume
91
Category
Article
ISSN
0037-9646

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The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we