Structure and Reactions of Glycopyranoside Derived Dialdehydes
β Scribed by Thorsten Heidelberg; Prof. Dr. Joachim Thiem
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 936 KB
- Volume
- 340
- Category
- Article
- ISSN
- 1615-4150
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π SIMILAR VOLUMES
The anomerization reactions of permethylated methyl o-glycopyranosides in the presence of various Lewis acid catalysts, such as Me,SiOTf, Me,SiOMs, BF,.OEt,, or TiCI, were examined in dichloromethane solution. p Anomers of the glycosides anomerized to the (Y anomer very rapidly, but the anomerizatio
## Abstract Reaction of different glycosyl donors with 5βhydroxyβ__N__βmethylβ2,3βdiphenylindole (1C) led only to __O__βglycosylation (compounds 6aβc and 8cβΞ±,Ξ²). Depending on the __O__βprotection of the glycosyl donors (2aβc, 3b, 4c), the Ξ²βproducts were obtained mainly or exclusively. The corresp