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Structure and properties of thiolatorhodium complexes, Rh(SC6H4-p-X)(PMe3)3 (X = Me, OMe)

✍ Scribed by Osakada, Kohtaro; Hataya, Kouji; Yamamoto, Takakazu


Book ID
127139701
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
644 KB
Volume
12
Category
Article
ISSN
0276-7333

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The sandwich complexes bis(q6-naphthalene)molybdenum(O) (l), bis(q6-1-methylnaphtha1ene)molybdenum(0) (Z), and bis(q6-1,4-dirnethylnaphthalene)molybdenum(O) (3) are synthesized by cocondensation of Mo-atoms with the naphthalene ligands. Complexes 1-3 are also obtained by reduction of MoCI, or MoCl4.