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Structure and properties of the one-dimensional cobalt oxide CaCo2O4

✍ Scribed by M. Isobe; M. Arai; T. Kawashima; E. Takayama-Muromachi


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
479 KB
Volume
469
Category
Article
ISSN
0921-4534

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The hexagonal perovskite solid solution Ba 1 \ x Sr x CoO 3 (04x40.5) was synthesized by treatment of cubic perovskite precursors at 5003C in high-pressure oxygen. The structure consists of parallel chains of face-sharing CoO octahedra and alkaline-earth ion separators. All materials were found to b