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Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C 52 H 60 NO 12 ) 12 [(Mn(H 2 O)) 3 (SbW 9 O 33 ) 2 ], a First Generation Dendrizyme

✍ Scribed by Volkmer, Dirk; Bredenkötter, Björn; Tellenbröker, Jörg; Kögerler, Paul; Kurth, Dirk G.; Lehmann, Pit; Schnablegger, Heimo; Schwahn, Dietmar; Piepenbrink, Markus; Krebs, Bernt

Book ID
121015790
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
472 KB
Volume
124
Category
Article
ISSN
0002-7863

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✍ Yang-Yi Yang; Xiao-Ming Chen; Seik Weng Ng 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 369 KB

Two new octadecanuclear clusters [Cu 12 Ln 6 ( 3 -OH) 24 (C 5 H 5 NCH 2 CO 2 ) 12 (H 2 O) 18 ( 9 -NO 3 )] (PF 6 ) 10 (NO 3 ) 7 ' 12H 2 O [Ln III ‫؍‬ Sm III (1) or Gd III (2)] have been synthesized and characterized by X-ray di4raction. They are isomorphous and crystallize in the triclinic space grou