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Structure and Properties of Tetracyanomanganate(II), [MnII(CN)4]2−, The First Paramagnetic Tetrahedral Cyanometalate Complex

✍ Scribed by Wayne E. Buschmann; Atta M. Arif; Joel S. Miller


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
137 KB
Volume
37
Category
Article
ISSN
0044-8249

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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~