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Structure and properties of nonstoichiometric mixed perovskites A3B′1+xB″2−xO9−δ

✍ Scribed by Shanwen Tao; John T.S. Irvine


Book ID
108409886
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
284 KB
Volume
154-155
Category
Article
ISSN
0167-2738

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Synthesis, Structure, and Physical Prope
✍ Vicent Primo-Martı́n; Martin Jansen 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 226 KB

The perovskites Sr 3 CoSb 2 O 9 , Sr 2 CoSbO 6 , and Sr 2 CoSbO 5.63 have been synthesized in polycrystalline form by solid state reactions from acetate precursors as obtained by freeze-drying. The crystal structure of insulating Sr 3 CoSb 2 O 9 has been re5ned from X-ray data by the Rietveld method