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Structure and properties of ethyl (2-benzimidazolyl)cyanoacetimidate

✍ Scribed by Yoshimi Yamaguchi; Yoshihisa Okamoto; Kazuho Harada


Book ID
102341352
Publisher
Journal of Heterocyclic Chemistry
Year
1999
Tongue
English
Weight
302 KB
Volume
36
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

The revision of the structure of hydrolytic product from 4‐cyano‐1‐ethoxypyrirnido[1,6‐a]benzimidazole (1) and the properties of ethyl (2‐benzimidazolyl)cyanoacetimidate (3a) are described.


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A new dinuclear iron nitrosyl complex [Fe(2)(C(14)H(12)N(3)S)(2)(NO)(4)] (1) (C(14)H(12)N(3)S = 2-mercapto-1-[2-(4-pyridyl)-ethyl]-benzimidazolyl) has been obtained by the reaction of Fe(NO)(2)(CO)(2) with 2-mercapto-1-[2-(4-pyridyl)-ethyl]-benzimidazole in CH(3)OH under moderate condition. Complex