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Structure and O2uptake properties of a novel nickel(II) complex of pyridyl-pendant dioxocyclam [1-(2-pyridyl)methyl-5,7-dioxo-1,4,8,11-tetraazacyclotetradecane]

✍ Scribed by E. Kimura; Masatoshi Sasada; Mitsuhiko Shionoya; Tohru Koike; Hiromasa Kurosaki; Motoo Shiro

Book ID: 106232805
Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 315 KB
Volume: 2
Category: Article
ISSN: 1432-1327
DOI: 10.1007/s007750050108

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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~