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Structure and Magnetism of 3D Anionic Metal Dicyanamide (MePh 3 P)[M(dca) 3 ] (M = Fe, Co, Ni) and (EtPh 3 P)[M(dca) 3 ] (M = Mn, Co, Ni) Networks

✍ Scribed by van der Werff, Patricia M.; Batten, Stuart R.; Jensen, Paul; Moubaraki, Boujemaa; Murray, Keith S.; Cashion, John D.


Book ID
127025536
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
269 KB
Volume
4
Category
Article
ISSN
1528-7483

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Synthesis, Structural Isomerism, and Mag
✍ Paul Jensen; Stuart R. Batten; Boujemaa Moubaraki; Keith S. Murray πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 465 KB

The coordination polymers [M(dca) 2 pyz] (M ‫؍‬ Mn, Fe, Co, Ni, Zn) have been synthesized and characterized by singlecrystal and powder X-ray di4raction. Two isomers have been observed. The compounds contain two interpenetrating 3D -Po related networks. Bidentate dca ligands bridge the metal atoms t