Structure and magnetic properties of a new dinuclear nickel(II) complex with a dinucleating hexaazamacrocycle
β Scribed by Hai-Liang Zhu; Mei-Fang Wu; Li-Min Zheng; Pei Huang; Wen-Xia Tang; Wei-Ming Bu
- Book ID
- 110244758
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 122 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0340-4285
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The dinucleating macrocycles H,(Lm") containing two 2,6-di(aminomethyl)-4-methylphenol entities combined through two alkane chains, -(CH,),-(m=2, 3) and -(CH,),-(n=2, 3, 4, S), at the amine nitrogens, form mckeI(I1) complexes of the general formula [Nr2(Lmn)(OA~)2] ((m,n)=(2,2), (2,4), (2,5), (3,3))
## Abstract The synthesis and magnetic behavior of four new dinuclear iron(II) complexes Fe~2~2aβd Γ 4Py with the iron in an octahedral coordination sphere is presented in this paper. The complex **c** is a highβspin complex over the whole temperature range investigated, while the complexes **a,b**