The structures of purinophane 1 and its higher homolog 2 were determined by X-ray crystallographic analysis. Hypochromism of 1 and 2 in various media is reported.
Structure and hypochromism of (6,9) (9′,6′) purinophanes
✍ Scribed by Fumio Hama; Yoshiteru Sakata; Soichi Misumi; Misako Aida; Chikayoshi Nagata
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 202 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The.structure of the title compound la was determined to be a cross-stacking form with an interplanar distance of ca. 3.3 A by X-ray analysis. On the basis of this structure, the hypochromicity of la was calculated by the ASMO SCF CI method.
📜 SIMILAR VOLUMES
The amorphous phase of a series of random 6/6.9 copolyamides was investigated. It was characterized by the glass transition temperature (T,) and the hydrogen bond content, as a function of the copolymer composition, compared to the corresponding homopolymers, polyamide 6 and polyamide 6.9. The hydro