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Structure and equilibria in triorganolead halide adduct formation

✍ Scribed by Hilary J. Eppley; James L. Ealy; Claude H. Yoder; J.N. Spencer; Arnold L. Rheingold

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 560 KB
Volume: 431
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(92)80112-b

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## Abstract The adducts of niobium(V) and tantalum(V) halides with some phosphoryl compounds have been studied in chloroform solution by ^1^H‐ and ^19^F‐FT‐NMR. spectroscopy. These octahedral adducts of general formula MX~5~ · L (M = Nb, Ta; X = F, Cl, Br; L = phosphoryl ligand) are monomeric and n