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Structure and Enhanced Reactivity Rates of the D 5 h Sc 3 N@C 80 and Lu 3 N@C 80 Metallofullerene Isomers: The Importance of the Pyracylene Motif

✍ Scribed by Cai, Ting; Xu, Liaosa; Anderson, Mark R.; Ge, Zhongxin; Zuo, Tianming; Wang, Xuelei; Olmstead, Marilyn M.; Balch, Alan L.; Gibson, Harry W.; Dorn, Harry C.


Book ID
126126594
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
540 KB
Volume
128
Category
Article
ISSN
0002-7863

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An isomer of the endohedral metallofulle
✍ James C. Duchamp; Aline Demortier; Kerra R. Fletcher; Daniel Dorn; Erick B. Iezz πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 238 KB

The discovery of a new isomer of the endohedral metallofullerene Sc 3 N@C 80 is reported. 13 C labeled ($9%) Sc 3 N@C 80 has been synthesized and has been characterized by HPLC, mass spectroscopy and 13 C NMR data. The 13 C NMR spectrum shows six peaks with a 1:2:2:1:1:1 ratio that are assigned to t