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Structure and Electronic Properties of [Ni(dsdm){Fe(CO)3}2], an Unusual, Triangular Nickel Diiron Compound

✍ Scribed by Marie-Cécile Chalbot; Allison M. Mills; Anthony L. Spek; Gary J. Long; Elisabeth Bouwman


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
122 KB
Volume
2003
Category
Article
ISSN
1434-1948

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## Abstract Reaction of Ni(ClO~4~)~2~·6H~2~O with bis(3‐aminopropyl)amine (dpt) and ammonium thiocyanate produces the novel thiocyanato‐bridged nickel(II) compound [Ni(μ‐NCS)(dpt)(NCS)]~2~[Ni(μ‐NCS)(dpt)(NCS)]~4~, which has been structurally characterised. The structure determination reveals that t