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Structure and Electron Detachment Energies of Al 3 P - and Al 3 P 3-

✍ Scribed by Archibong, Edet F.; St-Amant, Alain; Goh, Sor Koon; Marynick, Dennis


Book ID
126890611
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
77 KB
Volume
106
Category
Article
ISSN
1089-5639

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EPR spectra of Al[P(CH3)3]2 and Al[P(OCH
✍ M. Histed; J.A. Howard; H.A. Joly; B. Mile πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 362 KB

EPR examination of the products of the reaction between Al atoms and P(CHs)s and P(OCHs)s on a rotating cryostat in hydrocarbon matrices at 77 K reveals the presence of the seven-electron binary complexes A1[P(CH&12 and Al[P(OCHX)3]2. The magnetic parameters of these complexes are consistent with b