Intramolecular and reorientation dynamic
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Rakhim R. Rakhimov; Nikolas P. Benetis; Anders Lund; Jimmy S. Hwang; Alexander I
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Article
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1996
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Elsevier Science
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English
โ 449 KB
Two simultaneous dynamical processes are studied in solutions of varying viscosity by using the EPR linewidth data of a Cu(I) o-semiquinone complex with two triphenylphosphine ligands (PPh3), i.e. the overall reorientation (tumbling) of the complex and intramolecular exchange of the PPh 3 ligands in