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Structure and Dynamics of Bis(triphenylphosphine)-3,6-di- tert -butyl- o -semiquinone Radical Anion Complexes of Ag + and Cu +

โœ Scribed by Rakhimov, Rakhim R.; Hawkins, Tamika N.; Hwang, Jimmy S.; Prokof'ev, Alexander I.; Aleksandrov, Aleksey I.


Book ID
126829606
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
107 KB
Volume
107
Category
Article
ISSN
1089-5639

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Intramolecular and reorientation dynamic
โœ Rakhim R. Rakhimov; Nikolas P. Benetis; Anders Lund; Jimmy S. Hwang; Alexander I ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 449 KB

Two simultaneous dynamical processes are studied in solutions of varying viscosity by using the EPR linewidth data of a Cu(I) o-semiquinone complex with two triphenylphosphine ligands (PPh3), i.e. the overall reorientation (tumbling) of the complex and intramolecular exchange of the PPh 3 ligands in