Structure and dynamics of aqueous solutions of tetramethylurea
β Scribed by L. Cser; B. Farago; T. Grosz; G. Jancso; Yu.M. Ostanevich
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 244 KB
- Volume
- 180-181
- Category
- Article
- ISSN
- 0921-4526
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β¦ Synopsis
Some microscopic properties of a tetramethylurea (TMU) water solution were investigated using neutron scattering methods. It was established that over the concentration range investigated a remarkable attractive contribution arises due to hydrophobic interaction. Orientational perturbation of the solvent around the TMU molecules was observed. All types of diffusional motion are inhibited and their concentration dependence is rather small.
π SIMILAR VOLUMES
## Abstract We performed several molecular dynamic studies of metal cations in aqueous solution. The alkali metal ion Li^+^ and the firstβrow transition metal ion Mn^2+^ have been chosen as model systems. Two different threeβbody corrections are proposed to mimic the crucial manyβbody effects of el