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Structure and dynamics of a primordial catalytic fold generated by in vitro evolution

✍ Scribed by Chao, Fa-An; Morelli, Aleardo; III, John C Haugner; Churchfield, Lewis; Hagmann, Leonardo N; Shi, Lei; Masterson, Larry R; Sarangi, Ritimukta; Veglia, Gianluigi; Seelig, Burckhard

Book ID: 118192882
Publisher: Nature Publishing Group
Year: 2012
Tongue: English
Weight: 926 KB
Volume: 9
Category: Article
ISSN: 1552-4450
DOI: 10.1038/nchembio.1138

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## Abstract Mastoparan‐X, a 14‐residue peptide found in wasp venom, does not adopt a well‐defined structure in water, but it folds into an α‐helix upon addition of trifluoroethanol (TFE). At low levels of TFE, the peptide is partially folded, passing through intermediate stages of folding as the am