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Structure and conformation of heterocycles III. Angularly and peripherally substituted cis-1,4,5,8-tetraoxadecalins.

✍ Scribed by Yehuda Auerbach; Milon Sprecher; Benzion Fuchs


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
231 KB
Volume
11
Category
Article
ISSN
0040-4039

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Structure and conformation of heterocycl
✍ Benzion Fuchs πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 230 KB

When ethylene glycol is condensed with an a-diketone (R-CO-CO-R) in an acid catalyzed reaction, a mixture of two isomers is usually obtained (2). Interestingly enough, the structural assignments of the parent compounds (R-H), Isomers A and B, were a matter of dispute over a period of more then thirt