✦ LIBER ✦

Structure and Conformation of Bis(trifluoromethylthio)methane, CH2(SCF3)2

✍ Scribed by Korn, Monika ;Haas, Alois ;Oberhammer, Heinz

Publisher: Wiley (John Wiley & Sons)
Year: 1995
Tongue: English
Weight: 353 KB
Volume: 128
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19951280505

No coin nor oath required. For personal study only.

✦ Synopsis

Bis(trifluoromethy1thio)methane / Gas-phase structure / Conformational properties / Electron diffraction / Calculations, ab initio

The geometric structure and conformational properties of stances r, [pm] and angles L, ["I with 3-0 uncertainties) were bis(trifluoromethylthio)methane, CH2(SCF3)2, were determi-obtained: C-S 183.6(3), S-CF3 179.3(3), S-C-S 112.1(6), ned by gas electron diffraction. The main conformer (70 f and C-S-C 98.2(10). The geometric structures and relative 15%) possesses Cz symmetry with dihedral angles conformational stabilities were well reproduced by ab initio @ ( S C S C ) = 79.1(10)". The second conformer possesses C1 calculations at the HF/3-21G* level. symmetry. The following skeletal geometric parameters (di-

📜 SIMILAR VOLUMES

Vibrational spectroscopic studies, confo

Vibrational spectroscopic studies, conformations and ab initio calculations of 1,2-bis(trifluorosilyl)ethane (SiF3CH2CH2SiF3)

✍ Peter Klaeboe; Claus J. Nielsen; Anne Horn; Gamil A. Guirgis; Kathleen V. Kilway 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 289 KB

Conformational diversity in the solid st

Conformational diversity in the solid state structures of [Rh2(μ-CH3N(P(OCH3)2)2)2(CH3N(P(OCH3)2)2)2]X2 (X = O3SCF3, B(C6H5)4)

✍ Joel T. Mague 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 810 KB

Crystal Structure of Bi(OCMe2CH2OMe)3 an

Crystal Structure of Bi(OCMe2CH2OMe)3 and Its Use in the MOCVD of Bi2O3

✍ P. A. Williams; A. C. Jones; M. J. Crosbie; P. J. Wright; J. F. Bickley; A. Stei 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 354 KB 👁 2 views

Synthesis and Crystal Structure of Bismu

Synthesis and Crystal Structure of Bismuth(III) Complexes Bi(1,10-phen)[S2CN(CH3)2]2(NO3), {Bi(S2COCH2)[S2CNC6H5(CH3)]2}2 and [Bi(S2CNBu2)2(CH3OH)(NO3)]∞

✍ Han-Dong Yin; Chuan-Hua Wang; Qiu-Ju Xing 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB

Crystal Structures of CH2 = CHCH2OC(O)CH

Crystal Structures of CH2 = CHCH2OC(O)CH2CH2SnCl3.OPPh3 and BuOC(O)CH(CH3)CH2SnCl3.OPPh3

✍ Marcel Gielen; Huade Pan; Edward R. T. Tiekink 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 344 KB 👁 1 views

Synthesis and characterization of the co

Synthesis and characterization of the complexes of Mo(V) and Mo(VI) with the ligands HSCH2CH2N(CH3)(CH3)(CH3)CH2CH2SH, n = 2,3. The crystal structure of H2[Mo2O4(SCH2CH2N(CH3) (CH2)3N(CH3) (CH2)3N(CH3)CH2CH2S)2]

✍ N. Kim; S. Kim; P.A. Vella; Jon Zubieta 📂 Article 📅 1978 🏛 Elsevier Science ⚖ 311 KB