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Structure and Chain Dynamics of Alkanethiol-Capped Gold Colloids

✍ Scribed by Badia, A.; Gao, W.; Singh, S.; Demers, L.; Cuccia, L.; Reven, L.

Book ID: 121322841
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 322 KB
Volume: 12
Category: Article
ISSN: 0743-7463
DOI: 10.1021/la9510487

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## Abstract The homoleptic gold(I) thiolates of formula [Au(SR)]__~n~__ (R = CMe~3~, CH~2~CMe~3~, CH~2~CHMe~2~, CPh~3~) have been converted into their phosphane derivatives of general formula [Au(SR)(L)] (L = PMe~3~, PMe~2~Ph, PMePh~2~, PPh~3~) and [Au~2~(SR)~2~(dppe)] [dppe = 1,2‐bis(diphenylphosp