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Structure and Bonding in Stannadiphospholes and their Dianions SnC2P2R2m (R=H, tBu m=0, −2): A Comparative Study with C5H5+ and C5H5− Analogues

✍ Scribed by K. Harikrishna Reddy; Dr. Dandamudi Usharani; Prof. John F. Nixon; Prof. Eluvathingal D. Jemmis

Book ID
102794957
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
743 KB
Volume
17
Category
Article
ISSN
0947-6539

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## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C