Structure and bonding in small aluminum clusters
β Scribed by Jones, R. O.
- Book ID
- 121399259
- Publisher
- The American Physical Society
- Year
- 1991
- Tongue
- English
- Weight
- 183 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0031-9007
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π SIMILAR VOLUMES
Small Sin and Al, clusters (n = 3-10) were studied with the semiempirical molecular orbital method (MO) method SINDO1. For each n, various structures were optimized to determine the most stable structure. To obtain good qualitative agreement with available ab initio calculations d orbitals had to be
Photoelectron spectra of Al; (n = 2-20) clusters are presented. Due to the improved energy resolution and the relatively high photon energy (hv= 6.424 eV, ArF laser radiation) available in our experiment the spectra reveal the mechanism of the onset of the s-p hybridization occuring in these particl