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Structure and bonding in bis(quinone) complexes of ruthenium. Synthesis and characterization of the Ru(PPh3)2(SQ)2 (SQ = 3,5-tert-butylsemiquinone, tetrachloro-1,2-semiquinone) series

โœ Scribed by Bhattacharya, Samaresh.; Pierpont, Cortlandt G.

Book ID
127330795
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
710 KB
Volume
30
Category
Article
ISSN
0020-1669

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On reaction of 1,2-bis(2-pyridylmethylthio)-bis-ethylsulphide (L) with copper(II) chloride in presence of an excess of azide ions led to the formation of a new copper(II) complex formulated as [Cu(2-PTrz) 2 (H 2 O) 2 ] (1), where 2-PTrz = 5-(2-pyridyl)-1,3,4-triazole is formed through the cleavage o