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Structure and absolute configuration of the sesquiterpenoid emmotins

✍ Scribed by Alaíde B. De Oliveira; Geovane G. De Oliveira; Catarina T.M. Liberalli; Otto R. Gottlieb; Mauro T. Magalhaes


Book ID
107841834
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
722 KB
Volume
15
Category
Article
ISSN
0031-9422

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6S,10S)-3,10- Dimethyl-7,11-dimethylidenespiro[5,5]undec-2-en-4-one (1), a new rearranged chamigrane-type sesquiterpenoid with two sp 2 -hybridized carbons in α-positions to the spiro-atom, was isolated from the alcoholic extract of the sea hare Aplysia sp. and its structure and absolute configurati