Structure analysis of Mo/Ni superlattice
โ Scribed by Guo-Guang Zheng; Hui Xia; Yan-Zhen Wei; Jia-Qi Zheng
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 400 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0749-6036
No coin nor oath required. For personal study only.
โฆ Synopsis
A Mo/Ni superlattice with a modulation wavelength A = 52 A was prepared using magnetron sputtering.
It was shown by x-ray diffraction and ion milling Auger electron spectroscopy that the sample was compositionally modulated and that the thickness of the individual layers was uniform. A cubic structure was observed with ultrahigh voltage electron diffraction.
The crystal structures of the Mo and Ni in the superlattice did not change, however their lattice constants were both expanded.
The lattice constants of the Mo and Ni were both 3.73 ~, and growth was in the [111] direction. I.
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A series of boron-modified commercial Ni-Mo/A1203 hydrotreating catalysts have been characterized by IR analysis of adsorbed NO and pyridine and by gas-oil sulfur-and nitrogen-removal activities. Sulfur removal activity was found to correlate with the 1690 cm -1 (Mo(NO)22รท) band in the NO adsorption