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Structurally selective stereospecific cyclization of E,E,E,E-geranylfarnesol and its acetate by fluorosulfonic acid

โœ Scribed by P. F. Vlad; N. D. Ungur; Nguyen Hung


Publisher
Springer
Year
1988
Tongue
English
Weight
112 KB
Volume
24
Category
Article
ISSN
0009-3130

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A stereospecific synthesis of conjugated
โœ G. Cassani; P. Massardo; P. Piccardi ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

The reaction of (E)-1-alkenylboronic acids with (Z)-or(E)-1-alkenyl iodides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium and sodium hydroxide gave the corresponding conjugated (E,E)-or (E,E)--alkadienes with high stereospecificity. Cross-coupling reactions between 1