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Structural variations of nickel complexes in NiS4and NiS2PN coordination environments: spectral and single-crystal X-ray structural studies on bis(4-methylpiperidinecarbodithioato-S,S′)nickel(II) and (4-methylpiperidinecarbodithioato-S,S′)(thiocyanato-N)(triphenylphosphine)nickel(II)

✍ Scribed by N. Srinivasan; V. Sathyaselvabala; K. Kuppulekshmy; P. Valarmathi; S. Thirumaran


Publisher
Springer Vienna
Year
2009
Tongue
English
Weight
275 KB
Volume
140
Category
Article
ISSN
0026-9247

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X-ray photoelectron spectral study was made on the complexes Ni(nmedtc) 2 (1), [Ni(nmedtc)(PPh 3 ) 2 ]ClO 4 (2), [Ni-(nmedtc)(dppe)]BPh 4 (3) (where nmedtc ϭ N-methyl,N-ethanoldithiocarbamate, dppe ϭ 1,2-bis(diphenylphosphino)ethane). The nickel 2p 3/2 binding energy values for chelated and free pho