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Structural types of double pyrophosphates with the general formula A+M3+P2O7

✍ Scribed by E. A. Genkina


Publisher
SP MAIK Nauka/Interperiodica
Year
1991
Tongue
English
Weight
379 KB
Volume
31
Category
Article
ISSN
0022-4766

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Stabilization of a W(V) Diphosphate, W2O
✍ A. Leclaire; J. Chardon; B. Raveau πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 305 KB

A new form of WPO 5 has been synthesized which is to our knowledge the second pentavalent tungsten phosphate actually known. This phase is isotypic to CsP 8 W 8 O 40 and consequently can be described as a tungsten diphosphate, W 2 O 3 ' P 2 O 7 , with large empty eight-sided tunnels. Although it fun