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Structural trends in bis(pentamethylcyclopentadienyl)lanthanide and yttrium complexes

✍ Scribed by William J. Evans; Samuel E. Foster


Book ID
107812139
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
792 KB
Volume
433
Category
Article
ISSN
0022-328X

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Syntheses and structure of bis(pentameth
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## Bis(pentamethylcyclopentadienyl)phosphane Cp\* 2 PH reacts with sulfur under basic conditions to give the corresponding dithiophosphinate salts M ‫ם‬ (5 β€«Χžβ€¬ CP\* PS 2 2 M ‫ם‬ ‫ב‬ , 6 M ‫ם‬ ‫ב‬ Li ‫ם‬ ), which are formed via the ‫ם‬ HNEt 3 intermediate CP\* 2 P(S)H (4). Both salts on treatment wi