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Structural, thermal and optical studies on 2-naphthol crystals

โœ Scribed by L. Guru Prasad; V. Krishnakumar; G. Shanmugam; R. Nagalakshmi


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
209 KB
Volume
45
Category
Article
ISSN
0232-1300

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โœฆ Synopsis


Abstract

Single crystals of 2โ€naphthol was grown in slow evaporation solution growth technique. Grown crystals were characterized by various characterization techniques. Powder Xโ€ ray diffraction studies reveal that the grown crystal belongs to monoclinic system with noncentrosymmetric space group. Vibrational bands of the various functional groups and their significance were investigated by analyzing the vibrational spectra. Melting point and the decomposition temperature of the grown crystal was premeditated from the thermal analysis. From the UVโ€VISโ€NIR spectrum the electronic excitation mechanism and the transmittance abilities of the crystal was studied. Theoretical value of first static hyperpolarizability was calculated and compared with urea. Second harmonic generation efficiency of the crystal is 0.6 times that of KDP. (ยฉ 2010 WILEYโ€VCH Verlag GmbH & Co. KGaA, Weinheim)


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