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Structural study of the dehydration of templated zirconium phosphate fluorides

✍ Scribed by Martin Wloka; Sergey Troyanov; Erhard Kemnitz

Book ID
114370494
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
635 KB
Volume
4
Category
Article
ISSN
1293-2558

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Organically Templated Zirconium Fluoride
Organically Templated Zirconium Fluorides: Hydrothermal Syntheses, Structural Relationships, and Thermal Behavior of (C2H10N2)Zr2F10Β·H2O and (C4H12N2)ZrF6Β·H2O
✍ Richard E. Sykora; Michael Ruf; Thomas E. Albrecht-Schmitt πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 403 KB

The organically templated Zr(IV) 6uorides, (C 2 H 10 N 2 ) Zr 2 F 10 ' H 2 O (AU2-6) and (C 4 H 12 N 2 )ZrF 6 ' H 2 O (AU1-6) have been prepared from the reaction of ZrO 2 with HF and ethylenediamine or piperazine under mild hydrothermal conditions. These compounds were characterized by single-cryst