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Structural study of poly(vinyl alcohol) in the gel state by high-resolution solid-state 13C NMR spectroscopy

✍ Scribed by Kobayashi, Masatoshi; Ando, Isao; Ishii, Takahiro; Amiya, Shigetoshi


Book ID
127161351
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
285 KB
Volume
28
Category
Article
ISSN
0024-9297

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Poly(vinyl alcohol) (PVA) with 55% and 61% syndiotacticity, and their related dry and hydrated gels obtained by two different freeze-thawing cycles have been investigated using the solid-state 13C CP-MAS NMR technique. From a comparative analysis of the spectra, evidence was obtained that the gelati