Structural studies on taurocyamine: 2-[(aminoiminomethyl)-amino]-ethanesulfonic acid
β Scribed by G. Bombieri; F. Demartin; D. Braghiroli; M. Di Bella
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 279 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1572-8854
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## Abstract This paper describes the synthesis and structural studies of __N__β(__p__βtoluenesulfonyl)βamino acid 3,5βdiβ__tert__βbutylβ2βphenolamides by ^1^H, ^13^C, and ^15^N. The presence of __intra__β and __inter__molecular hydrogen bonds were studied by variable temperature NMR spectroscopy. T
A novel cycloetherification process involving a facile 5-exo S N 2-type ring closure by intramolecular opening of a terminal aziridine ring by a g-hydroxyl group, led to the stereoselective synthesis of 6-amino-2,5-anhydro-6-deoxy-D-mannonic acid (1). Oligomerization of 1 by solution phase peptide c