Structural studies of the intercalation complexes titanium sulfide-ammonia (TiS2.NH3) and tantalum sulfide-ammonia (TaS2.NH3)
β Scribed by Chianelli, R. R.; Scanlon, J. C.; Whittingham, M. S.; Gamble, F. R.
- Book ID
- 127346974
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 733 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
## Structure D 2000 First Characterization of an Extended Ammonium-Ammonia Complex 1 β [{NH4(NH3)4} + (Β΅-NH3)2] in the Crystal Structure of [NH4(NH3)4][Co(C2B9H11)2]β’2NH3. -The title compound is prepared by reaction of Na[Co(C2B9H11)2] with a proton-charged ion exchange resin in liq. NH3 (Amberlys
Ab initio calculations ~vc the equilibrium stn~cturc 01 the ammonia dimcr czuion as a complcn between the ammonium ion (N;if ) and the aminyl radical (NH2). Dissocialion energies of this calion are e~~lua~cd IO be about 1.0 and 1.7 CV [or the wo signiticant channels inlo NH; +NH, and NH, +NH;. respe