Structural Studies of Crystalline Pentacalent Organobismuth Compounds

✍ Scribed by Derek H. R. Barton; Brigitte Charpiot; Elise Tran Huu Dau; William B. Motherwell; Claudine Pascard; Clotilde Pichon

• Publisher: John Wiley and Sons
• Year: 1984
• Tongue: German
• Weight: 661 KB
• Volume: 67
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19840670227

✦ Synopsis

Abstract

The syntheses and X‐Ray analyses of three pentavalent organobismuth compounds are described; one of these compounds has a novel diphenylbis(trifluoroacetato)‐bismuthate anion with trigonal bipyramidal geometry and a stereochemically active lone pair. Analysis of these structures together with other data from the literature allows a mapping of the reaction coordinate for bismuth polyhedra.