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Structural Rigidity and Luminescence of Chiral Lanthanide Tetraamide Complexes Based on 1,4,7,10-Tetraazacyclododecane

✍ Scribed by Rachel S. Dickins; Prof. Judith A. K. Howard; Dr. Christian W. Lehmann; Janet Moloney; Prof. David Parker; Dr. Robert D. Peacock

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
374 KB
Volume
36
Category
Article
ISSN
0044-8249

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✦ Synopsis

Substitution reactions of 1 he square-planar complexes are typically associative: R. J. Cross, A h , . Inorg. Chem. 1989, 34, 219. [23] Palladium(n) halide complexes o f general formula [RPdC1(N-N')(q2-alkene)] are well known and have been crystallographically characterized: V. G. Albano, C. Caatellari. M. E. Cucciolito, A. Panuzi, A. Vitnlgliano, Orgunonzelulhc,y, 1990. 9. 1269. [24] This step could he either the formation of a pentacoordinate intermediate from 5 or the evolution of a pentacoordinate intermediate to 7. The first irreversible enantiodifferentiating step would determine asymmetric induction: C. R. Landis, J. Halpern, J An7. Chem. Soc. 1987, IOY, 425. [25] There arc scattered reports of various effects of halide additives on Heck reactions o f triflates: a) modified regioselection: C M.

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