An analysis of existing 13 C NMR data shows that the structures reported for the iridoid glucosides ajugol and myoporoside should be interchanged. Consequently, the structures of ajugoside and laterioside, both acyl-derivatives of ajugol. as well as that of 8-O-acetylmyoporoside need revision.
✦ LIBER ✦
Structural revision of barlerin and acetyl barlerin
✍ Scribed by Søren Damtoft; Søren Rosendal Jensen; Bent Juhl Nielsen
- Book ID
- 104221692
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 112 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
IH-and I3 C-NMR data as well as chemical evidence show that the structures of barlerm and acetyl barlerm should be corrected to 8-0-acetyl shanzhlslde methylester and 6, 8-di-O-acetyl-shanzhiside methylester, respectively.
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