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Structural requirement for catalytic activity of cobalt Schiff base complex in oxygenation of alkenes

✍ Scribed by Maruyama, K. ;Tsutsui, T. ;Shiosaki, H. ;Fujii, Y. ;Nishinaga, A.

Book ID
112691053
Publisher
Springer
Year
1993
Tongue
English
Weight
214 KB
Volume
49
Category
Article
ISSN
0133-1736

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The oxygenation of styrene catalyzed by optically active cobalt Schiff base complexes in 2-propanol gives an enantiomer excess of l-phenylethanol. The asymmetric induction may be accomplished in two steps: addition of CoH species to styrene and decomposition of 1-phenylethyl hydroperoxide. Cobalt Sc