Structural Relationships, Interconversion, and Optical Properties of the Uranyl Iodates, UO 2 (IO 3 ) 2 and UO 2 (IO 3 ) 2 (H 2 O): A Comparison of Reactions under Mild and Supercritical Conditions
β Scribed by Bean, Amanda C.; Peper, Shane M.; Albrecht-Schmitt, Thomas E.
- Book ID
- 121254051
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 125 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0897-4756
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The reactions of UO 3 and I 2 O 5 with RbCl, TlCl, SrCl 2 , or Pb(NO 3 ) 2 at 2003 3C for 3 days in aqueous media result in the formation of A 2 [(UO 2 ) 3 (IO 3 ) 4 O 2 ] (A β«Ψβ¬ Rb (1), Tl (2)) and AE[(UO 2 ) 2 (IO 3 ) 2 O 2 ](H 2 O) (AE β«Ψβ¬ Sr (3), Pb, (4)). Compounds 1 and 2 are isostructural wit