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Structural Relationships, Interconversion, and Optical Properties of the Uranyl Iodates, UO 2 (IO 3 ) 2 and UO 2 (IO 3 ) 2 (H 2 O): A Comparison of Reactions under Mild and Supercritical Conditions

✍ Scribed by Bean, Amanda C.; Peper, Shane M.; Albrecht-Schmitt, Thomas E.


Book ID
121254051
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
125 KB
Volume
13
Category
Article
ISSN
0897-4756

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ChemInform Abstract: Excision of Uranium
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Cation Effects on the Formation of the O
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The reactions of UO 3 and I 2 O 5 with RbCl, TlCl, SrCl 2 , or Pb(NO 3 ) 2 at 2003 3C for 3 days in aqueous media result in the formation of A 2 [(UO 2 ) 3 (IO 3 ) 4 O 2 ] (A ‫؍‬ Rb (1), Tl (2)) and AE[(UO 2 ) 2 (IO 3 ) 2 O 2 ](H 2 O) (AE ‫؍‬ Sr (3), Pb, (4)). Compounds 1 and 2 are isostructural wit