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Structural reinforcement of a large macrocyclic ligand. A structural, molecular mechanics, and thermodynamic study

✍ Scribed by Wade, Peter W.; Hancock, Robert D.; Boeyens, Jan C. A.; Dobson, Susan M.


Book ID
125828952
Publisher
The Royal Society of Chemistry
Year
1990
Tongue
English
Weight
647 KB
Volume
2
Category
Article
ISSN
1472-7773

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Two macrocyclic polyether isomers were obtained by radical cyclization of (E)-8-iodo-3,6-dioxaoctyl-3ethoxycarbonylpropenoate and separated by liquid-solid chromatography over silica gel. They were characterized, for the Ðrst time, by two-dimensional NMR ; notably, the HMBC experiment gave access to