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Structural Phase Transitions in KFeF4 and Related Materials

✍ Scribed by Saint-Grégoire, P. ;Almairac, R. ;Lapasset, J. ;Moret, J.

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 230 KB
Volume: 120
Category: Article
ISSN: 0031-8965
DOI: 10.1002/pssa.2211200132

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Structural Phase Transitions in Langbein

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Using Landau theory of phase transitions it is shown that in the langbeinite structure (space group T4) four spatially homogeneous structural phase transitions are possible. 'Three of them are improper ferroelectric and result from a phonon instability at the M point of the Brillouin zone. The fourt