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Structural phase transitions in dimethylammonium perchlorate

✍ Scribed by T.K.K. Srinivasan; M. Mylrajan

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
350 KB
Volume
182
Category
Article
ISSN
0009-2614

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✦ Synopsis

Raman and infrared spectra (20-5000 cm-') of ( CH3),NH2C104 and its N-deuterated analogue were investigated in the temperature range 90-350 K. A temperature dependent study of widths and frequencies of prominent bands confirms (a) the existence of phase transitions at 309 and 311 K and (b) in the high temperature phases II and I, the cations and anions undergo reorientational motions.

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