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Structural motifs of diiodine complexes with amides and thioamides

✍ Scribed by Parigoridi, Ioanna-Efpraxia; Corban, Ghada J.; Hadjikakou, Sotiris K.; Hadjiliadis, Nick; Kourkoumelis, Nikolaos; Kostakis, George; Psycharis, Vassilis; Raptopoulou, Catherine P.; Kubicki, Maciej


Book ID
118157205
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
219 KB
Volume
38
Category
Article
ISSN
1477-9226

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Basicity of azoles: complexes of diiodin
✍ M. J. El Ghomari; R. Mokhlisse; C. Laurence; J.-Y. Le Questel; M. Berthelot πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 123 KB πŸ‘ 1 views

The diiodine basicity (a soft Lewis basicity) of 15 azoles (imidazoles, pyrazoles and triazoles) was measured by means of the formation constant of the diiodine-azole complexes in heptane at 298 K. The preferred sites of diiodine fixation are the nitrogens N-3 in imidazoles, N-2 in pyrazoles and N-4