Structural Manifestations of the Retro Diels−Alder Reaction
✍ Scribed by Pool, Brett R.; White, Jonathan M.
- Book ID
- 115491918
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 41 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1523-7060
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The widespread application of the retro-Diels-Alder reaction in synthesis has been hampered by the high temperatures usually required to cffect cycloreversion. The discovery of the anionic oxy-Cope reaction was followed by predictions that the accclerating effect of the oxide anion should also be ob
The activation and reaction volumes (∆V /∆V) were showing negative volumes of activation (∆V Ͻ 0) whereas the others are slightly retarded (∆V Ͼ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum