Structural kinetic rules governing the thermal decomposition of pyridine N-oxides
β Scribed by O. R. Klyuchnikov; I. Sh. Saifullin; Yu. Yu. Nikishev
- Publisher
- Springer US
- Year
- 1994
- Tongue
- English
- Weight
- 243 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-3122
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## Abstract The kinetics of the pyrolysis of pyridine was studied in the temperature range of 875β1050Β°C, at 1 atm total pressure, in a Vycor stirredβflow reactor. Initial concentrations ranged from 0.25 to 2 mol % in helium and reaction times from 0.25 to 4 sec. It was found at the lower temperatu
The kinetics and mechanism of the thermal decomposition of n-propylsilane have been studied by the single pulse shock tube-comparative rate technique a t pressures around 4700 torr between 1095-1240 K. The primary dissociation processes are 1,l and 1,2 H, elimination with &,,, = 0.75 and &,,\* = 0.2