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Structural information from chemical shifts in lanthanide complexes

โœ Scribed by Jacques Reuben

Book ID
103191161
Publisher
Elsevier Science
Year
1982
Weight
293 KB
Volume
50
Category
Article
ISSN
0022-2364

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Large lanthanide-induced chemical shifts
Large lanthanide-induced chemical shifts in cobalt complexes of enethials (ฮฑ,ฮฒ-unsaturated thioaldehydes)
โœ Donald C. Dittmer; Edward Joseph Parker; James R. Bodwell ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 346 KB

Eu(fod),-, Yb(fod),-and Pr(fod),-induced chemical shifts of the 'thioaldehydic' protons in enethial ligands complexed to a cobalt cyclopentadienyl group are unusually large and in the same direction (1030ppm downfield per mole of shift reagent per mole of substrate). The shifts of the protons induce