Structural Influence of the Ligand Geometry on Construction of Coordination Polymers Formed from Silver(I) Chloride Ribbons and Bipodal Nitrogen Donor Ligands

Solvation effect on the construction of

Solvation effect on the construction of coordination polymers containing a flexible four-pyridyl ligand. Synthesis and crystal structures of silver(I) complexes

✍ Sojung Lee; Kyung Hwan Park; Jungmin Ahn; Young-A Lee; Ok-Sang Jung 📂 Article 📅 2011 🏛 Elsevier Science 🌐 English ⚖ 617 KB

Construction of AgX (X À = ClO À 4 and BF À 4 ) with highly flexible N,N,N 0 ,N 0 -tetrakis(ethylisonicotinoyl)ethylendiamine (L) has been scrutinized for the weak argentophilic, Ag anion, and AgÁsolvent interactions. All such complexes afford coordination polymers consisting of 2:1 (Ag( and BF À 4