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Structural flexibility and intrinsic dynamics in the M2(2,6-ndc)2(dabco) (M = Ni, Cu, Co, Zn) metal–organic frameworks

✍ Scribed by Klein, Nicole; Hoffmann, Herbert C.; Cadiau, Amandine; Getzschmann, Juergen; Lohe, Martin R.; Paasch, Silvia; Heydenreich, Thomas; Adil, Karim; Senkovska, Irena; Brunner, Eike


Book ID
111696190
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
857 KB
Volume
22
Category
Article
ISSN
0959-9428

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## Abstract We report the synthesis, crystal structures, and spectral, thermal, and magnetic properties of a family of metal–organic perovskite ABX~3~, [C(NH~2~)~3~][M^II^(HCOO)~3~], in which A=C(NH~2~)~3~ is guanidinium, B=M is a divalent metal ion (Mn, Fe, Co, Ni, Cu, or Zn), and X is the formate